catena-Poly[hexaaqua-1κO,2κO,3κ4 O-(μ4-3,5-dicarboxylatopyrazol-1-ido-3′:1:2:3κ6 O 5:N 1,O 5′:N 2,O 3:O 3′)(μ2-3,5-dicarboxylatopyrazol-1-ido-1:2κ4 N 2,O 3:N 1,O 5)-1,2-dicopper(II)-3-manganese(II)]
نویسنده
چکیده
In the title compound, [Cu(2)Mn(C(5)HN(2)O(4))(2)(H(2)O)(6)](n), the Cu(II) ion is coordinated by two N atoms, two O atoms and one water O atom in a distorted square-pyramidal geometry. The Mn(II) ion is coordinated by two O atoms and four water O atoms in a distorted octa-hedral geometry. Two pyrazolyl-3,5-dicarboxyl-ate anions chelate to two copper ions, forming a dinuclear unit, which further connects the Mn(II )ions into chains extending along [100]. Both independent coordinated water mol-ecules on the Mn(II) ion are disordered in a 50:50 fashion.
منابع مشابه
catena-Poly[bis(μ4-adipato-1:2:1′:2′κ4 O 1:O 1′:O 4:O 4′)bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)]
In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxyl-ate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper(II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF mo...
متن کاملPoly[diaqua(μ4-3,5-dicarboxylatopyrazol-1-ido-κ6 N 1,O 5:N 2,O 3:O 3′:O 5,O 5′)lanthanum(III)]
In the title coordination polymer, [La(C(5)HN(2)O(4))(H(2)O)(2)](n), the lanthanum(III) metal centre is nine-coordinated, with a distorted tricapped trigonal prismatic geometry, by the O atoms of two water mol-ecules and by two N and five O atoms of two N,O-bidentate, one O,O'-bidentate and one O-mono-dentate 3,5-dicarb-oxyl-ato-pyra-zol-1-ide ligands. The polymeric three-dimensional structure ...
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The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia-zol-2-yl)hydrazonometh-yl]-6-methoxy-phenol ligands, a methanol mol-ecule and a nitrate ion. Both Cu(II) centres are penta-coordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N-H⋯O and O-H⋯O hydrogen bonds.
متن کاملPoly[diaqua(μ2-5-carboxypyridine-3-carboxylato-κ2 N:O 3)hemi(μ2-oxalato-κ4 O 1,O 2:O 1′,O 2′)(μ4-pyridine-3,5-dicarboxylato-κ4 N:O 3:O 3′:O 5)silver(I)terbium(III)]
In the title coordination polymer, [AgTb(C(7)H(3)NO(4))(C(7)H(4)NO(4))(C(2)O(4))(0.5)(H(2)O)(2)](n), the Tb(III) ion is eight-coordinated by three O atoms from three different pydc (H(2)pydc = pyridine-3,5-dicarboxylic acid) ligands, one O atom from one Hpydc ligand, two O atoms from one oxalate ligand and two water mol-ecules in a distorted square-anti-prismatic geometry. The Ag(I) ion is coor...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato-1κ4 O 6,O 1,O 1′,O 6′:2κ4 O 1,N,N′,O 1′}(methanol-1κO)(perchlorato-1κO)copper(II)sodium(I)
The mol-ecule of the title compound, [CuNa(C(18)H(18)N(2)O(4))(ClO(4))(CH(3)OH)], is almost planar with mean deviation of 5.2 (8)°. The coordination environment of the Cu(II) ion is distorted square-planar and it is N(2)O(2)-chelated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na atom is chelated by the four O atoms of the Schiff bas...
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